| Autor: |
Wu LK; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Feng Y; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Zou QH; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Jiang LL; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Wang ZJ; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Wang N; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Ye HY; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China., Li JR; Chaotic Matter Science Research Center, International Institute for Innovation, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China. |
| Abstrakt: |
Single-crystal membranes (SCMs) show great promise in the fields of sensors, light-emitting diodes, and photodetection. However, the growth of a large-area single-crystal membranes is challenging. We report a new organic-inorganic SCMs [HCMA] 2 CuBr 4 (HCMA = cyclohexanemethylamine) crystallized at the gas-liquid interface. It also has low-temperature ferromagnetic order, high-temperature dielectric anomalies, and narrow band gap indirect semiconductor properties. Specifically, the reversible phase transition of the compound occurs at 350/341 K on cooling/heating and exhibits dielectric anomalies and stable switching performance near the phase transition temperature. The ferromagnetic exchange interaction in the inorganic octahedra and the organic layer enables ferromagnetic ordering at low-temperature 10 K. Finally, the single crystal exhibits an indirect semiconducting property with a narrow band gap of 0.99 eV. Such rich multichannel physical properties make it a potential application in photodetection, information storage and sensors. |
