ZnFe 2 O 4 @SiO 2 @L-lysine@SO 3 H: preparation, characterization, and its catalytic applications in the oxidation of sulfides and synthesis of Bis(pyrazolyl)methanes.

Autor: Ghanbarpour A; Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran., Ghorbani-Choghamarani A; Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran. a.ghorbani@basu.ac.ir., Aghavandi H; Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran., Jafari A; Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran.
Jazyk: angličtina
Zdroj: Scientific reports [Sci Rep] 2024 Mar 28; Vol. 14 (1), pp. 7449. Date of Electronic Publication: 2024 Mar 28.
DOI: 10.1038/s41598-024-57317-2
Abstrakt: Herein, we report the synthesis of ZnFe 2 O 4 @SiO 2 @L-lysine@SO 3 H as a green, novel magnetic nanocatalyst, containing the sulfuric acid catalytic sites on the surface of zinc ferrite as the catalytic support. The physical and chemical properties of raw and modified samples (ZnFe 2 O 4 @SiO 2 @L-lysine@SO 3 H) were characterized by TGA, EDX, PXRD, Map, and FTIR analyses. The prepared nanocatalyst has excellent catalytic activity in synthesizing the oxidation of sulfides to the sulfoxides and Synthesis of pyrazolyl (Bis(pyrazolyl)methane) derivatives under green conditions. This designed nanocatalyst offers several advantages including the use of inexpensive materials and high yield, simple procedure, and commercially available. The synthesized mesoporous nanocatalyst was recovered and reused in five continuous cycles without considerable change in its catalytic activity.
(© 2024. The Author(s).)
Databáze: MEDLINE
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