Chemistry of Polythiols and Their Industrial Applications.

Autor: Hong SM; Department of Polymer Science & Engineering, Dankook University, Yongin 16890, Republic of Korea.; Advanced Materials Division, Shin-A T&C Co., Ltd., Seoul 08501, Republic of Korea., Kim OY; Department of Polymer Science & Engineering, Dankook University, Yongin 16890, Republic of Korea., Hwang SH; Department of Polymer Science & Engineering, Dankook University, Yongin 16890, Republic of Korea.
Jazyk: angličtina
Zdroj: Materials (Basel, Switzerland) [Materials (Basel)] 2024 Mar 14; Vol. 17 (6). Date of Electronic Publication: 2024 Mar 14.
DOI: 10.3390/ma17061343
Abstrakt: Thiols can react with readily available organic substrates under benign conditions, making them suitable for use in chemical, biological, physical, and materials and engineering research areas. In particular, the highly efficient thiol-based click reaction includes the reaction of radicals with electron-rich enes, Michael addition with electron-poor enes, carbonyl addition with isocyanate S N 2 ring opening with epoxies, and S N 2 nucleophilic substitution with halogens. This mini review provides insights into emerging venues for their industrial applications, especially for the applications of thiol-ene, thiol-isocyanate, and thiol-epoxy reactions, highlighting a brief chemistry of thiols as well as various approaches to polythiol synthesis.
Competing Interests: Author Seung-Mo Hong was employed by the company Shin-A T&C Co., Ltd. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
Databáze: MEDLINE
Externí odkaz:
Nepřihlášeným uživatelům se plný text nezobrazuje