| Autor: |
Zahn C; Department of Physics, Free University Berlin, Arnimallee 14, D-14195 Berlin, Germany., Pastore M; Université de Lorraine, CNRS, LPCT, F-54000 Nancy, France., Lustres JLP; Department of Physics, Free University Berlin, Arnimallee 14, D-14195 Berlin, Germany., Gros PC; Université de Lorraine, CNRS, L2CM, F-54000 Nancy, France., Haacke S; Université de Strasbourg─CNRS, IPCMS, 67034 Strasbourg, France., Heyne K; Department of Physics, Free University Berlin, Arnimallee 14, D-14195 Berlin, Germany. |
| Abstrakt: |
Tuning the photophysical properties of iron-based transition-metal complexes is crucial for their employment as photosensitizers in solar energy conversion. For the optimization of these new complexes, a detailed understanding of the excited-state deactivation paths is necessary. Here, we report femtosecond transient mid-IR spectroscopy data on a recently developed octahedral ligand-field enhancing [Fe(dqp) 2 ] 2+ ( C1 ) complex with dqp = 2,6-diquinolylpyridine and prototypical [Fe(bpy) 3 ] 2+ ( C0 ). By combining mid-IR spectroscopy with quantum chemical DFT calculations, we propose a method for disentangling the 5 Q 1 and 3 T 1 multiplicities of the long-lived metal-centered (MC) states, applicable to a variety of metal-organic iron complexes. Our results for C0 align well with the established assignment toward the 5 Q 1 , validating our approach. For C1 , we find that deactivation of the initially excited metal-to-ligand charge-transfer state leads to a population of a long-lived MC 5 Q 1 state. Analysis of transient changes in the mid-IR shows an ultrafast sub 200 fs rearrangement of ligand geometry for both complexes, accompanying the MLCT → MC deactivation. This confirms that the flexibility in the ligand sphere supports the stabilization of high spin states and plays a crucial role in the MLCT lifetime of metal-organic iron complexes. |
