Fluid fibers in true 3D ferroelectric liquids.

Autor: Jarosik A; Department of Nonlinear Phenomena, Institute of Physics, Otto von Guericke University, Magdeburg 39106, Germany., Nádasi H; Department of Nonlinear Phenomena, Institute of Physics, Otto von Guericke University, Magdeburg 39106, Germany., Schwidder M; Department Industrial Chemistry, Institute of Chemistry, Otto von Guericke University, Magdeburg 39106, Germany., Manabe A; Independent Researcher, Bensheim, Germany., Bremer M; Merck Electronics KGaA, Darmstadt 64293, Germany., Klasen-Memmer M; Merck Electronics KGaA, Darmstadt 64293, Germany., Eremin A; Department of Nonlinear Phenomena, Institute of Physics, Otto von Guericke University, Magdeburg 39106, Germany.
Jazyk: angličtina
Zdroj: Proceedings of the National Academy of Sciences of the United States of America [Proc Natl Acad Sci U S A] 2024 Mar 26; Vol. 121 (13), pp. e2313629121. Date of Electronic Publication: 2024 Mar 21.
DOI: 10.1073/pnas.2313629121
Abstrakt: We demonstrate an exceptional ability of a high-polarization 3D ferroelectric liquid to form freely suspended fluid fibers at room temperature. Unlike fluid threads in modulated smectics and columnar phases, where translational order is a prerequisite for forming liquid fibers, recently discovered ferroelectric nematic forms fibers with solely orientational molecular order. Additional stabilization mechanisms based on the polar nature of the mesophase are required for this. We propose a model for such a mechanism and show that these fibers demonstrate an exceptional nonlinear optical response and exhibit electric field-driven instabilities.
Competing Interests: Competing interests statement:The authors declare no competing interest.
Databáze: MEDLINE