(2,2'-Bi-pyridine-κ 2 N , N ')(4,4'-dimeth-oxy-2,2'-bipyridine-κ 2 N , N ')palladium(II) bis-(tri-fluoro-meth-anesulfonate).

Autor: Vargas BB; Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio, Texas 78209, USA., Arman HD; Department of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, USA., Adrian RA; Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio, Texas 78209, USA.
Jazyk: angličtina
Zdroj: IUCrData [IUCrdata] 2024 Feb 08; Vol. 9 (Pt 2), pp. x240109. Date of Electronic Publication: 2024 Feb 08 (Print Publication: 2024).
DOI: 10.1107/S2414314624001093
Abstrakt: In the title complex salt, [Pd(C 10 H 8 N 2 )(C 12 H 12 N 2 O 2 )](CF 3 SO 3 ) 2 , the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi-pyridine and 4,4'-dimeth-oxy-2,2'-bi-pyridine, in a distorted square-planar environment. In the crystal, weak π-π stacking inter-actions between the 2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4'-dimeth-oxy-2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.747 (18) Å] contribute to the alignment of the complex cations in columns parallel to the b -axis direction.
(© Vargas et al. 2024.)
Databáze: MEDLINE
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