Single Atom Catalyst in Persulfate Oxidation Reaction: From Atom Species to Substance.

Autor: Zhou D; Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou, 511443, P. R. China., Li Z; Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou, 511443, P. R. China., Hu X; College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha, 410004, P. R. China., Chen L; Department of General Practice, First Medical Center, Chinese PLA General Hospital, Beijing, 100853, P. R. China., Zhu M; Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou, 511443, P. R. China.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2024 Jul; Vol. 20 (30), pp. e2311691. Date of Electronic Publication: 2024 Mar 05.
DOI: 10.1002/smll.202311691
Abstrakt: With maximum utilization of active metal sites, more and more researchers have reported using single atom catalysts (SACs) to activate persulfate (PS) for organic pollutants removal. In SACs, single metal atoms (Fe, Co, Cu, Mn, etc.) and different substrates (porous carbon, biochar, graphene oxide, carbon nitride, MOF, MoS 2 , and others) are the basic structural. Metal single atoms, substances, and connected chemical bonds all have a great influence on the electronic structures that directly affect the activation process of PS and degradation efficiency to organic pollutants. However, there are few relevant reviews about the interaction between metal single atoms and substances during PS activation process. In this review, the SACs with different metal species and substrates are summarized to investigate the metal-support interaction and evaluate their effects on PS oxidation reaction process. Furthermore, how metal atoms and substrates affect the reactive species and degradation pathways are also discussed. Finally, the challenges and prospects of SACs in PS-AOPs are proposed.
(© 2024 Wiley‐VCH GmbH.)
Databáze: MEDLINE
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