Enhanced host-guest interaction between [10]cycloparaphenylene ([10]CPP) and [5]CPP by cationic charges.

Autor: Kayahara E; Institute for Chemical Research, Kyoto University, Uji 611-0011, Japan., Mizuhata Y; Institute for Chemical Research, Kyoto University, Uji 611-0011, Japan., Yamago S; Institute for Chemical Research, Kyoto University, Uji 611-0011, Japan.
Jazyk: angličtina
Zdroj: Beilstein journal of organic chemistry [Beilstein J Org Chem] 2024 Feb 23; Vol. 20, pp. 436-444. Date of Electronic Publication: 2024 Feb 23 (Print Publication: 2024).
DOI: 10.3762/bjoc.20.38
Abstrakt: A dication of [5]cycloparaphenylene ([5]CPP 2+ ) was selectively encapsulated by neutral [10]CPP to form the shortest double-layer carbon nanotube, [10]CPP⊃[5]CPP 2+ . While the same host-guest complex consisted of neutral CPPs, [10]CPP⊃[5]CPP, was already reported, the cationic complex showed an about 20 times higher association constant in (CDCl 2 ) 2 at 25 °C (10 3 mol L -1 ). Electrochemical and photophysical analyses and theoretical calculations suggested the partial electron transfer from [10]CPP to [5]CPP 2+ in the complex, and this charge-transfer (CT) interaction is most likely the origin of the higher association constant of the dicationic complex than the neutral one.
(Copyright © 2024, Kayahara et al.)
Databáze: MEDLINE
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