Exploring Heterotropones and Examining Their Propensity to Undergo [4 + 2] Cycloadditions.

Autor: Barløse CL; Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark., Faghtmann J; Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark., Kaasik M; Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark., Mastroddi R; Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark., Jørgensen KA; Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark.
Jazyk: angličtina
Zdroj: Organic letters [Org Lett] 2024 Mar 01; Vol. 26 (8), pp. 1539-1543. Date of Electronic Publication: 2024 Feb 16.
DOI: 10.1021/acs.orglett.3c04080
Abstrakt: An efficient strategy to obtain a broad array of chiral and achiral heterotropones and their corresponding [4 + 2] cycloadducts is disclosed. This strategy enables access to unique heterotropones and intricate bicyclic structures in high yields and diastereoselectivities through a simple procedure and from easily accessible starting materials.
Databáze: MEDLINE