Light-induced arylation (alkylation) of N -sulfonylhydrazones with boronic acids.

Autor: Junaid M; Department of Chemistry, Laboratory of Organic Synthesis & Catalysis Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand, India. yadagiri.dongari@cy.iitr.ac.in., Happy S; Department of Chemistry, Laboratory of Organic Synthesis & Catalysis Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand, India. yadagiri.dongari@cy.iitr.ac.in., Yadagiri D; Department of Chemistry, Laboratory of Organic Synthesis & Catalysis Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand, India. yadagiri.dongari@cy.iitr.ac.in.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Mar 05; Vol. 60 (20), pp. 2796-2799. Date of Electronic Publication: 2024 Mar 05.
DOI: 10.1039/d4cc00161c
Abstrakt: Di- and triarylmethanes are an important class of compounds in many fields. Here, we report an efficient light-induced arylation (alkylation) for the synthesis of diarylmethanes, bis(diarylmethyl)benzenes, arylalkylmethanes, and triarylmethanes from readily accessible N -sulfonylhydrazones and aryl/alkylboronic acids with the aid of Cs 2 CO 3 . In the presence of light, the synthesis of diarylmethanes was also achieved from aldehydes in a one-pot manner via a three-component approach in good yields. Furthermore, we have demonstrated the synthetic utility by synthesizing organoboron compounds and 2°-alcohol.
Databáze: MEDLINE