Embedding Pd into SnO 2 drastically enhances gas sensing.

Autor: Jabłczyńska K; Particle Technology Laboratory, Institute of Energy and Process Engineering, Department of Mechanical and Process Engineering, ETH Zurich CH-8092 Zurich Switzerland pratsinis@ethz.ch.; Faculty of Chemical and Process Engineering, Warsaw University of Technology 00-645 Warsaw Poland., Gogos A; Particles-Biology Interactions, Department of Materials Meet Life, Swiss Federal Laboratories for Materials Science and Technology (Empa) CH-9014 St. Gallen Switzerland.; Nanoparticle Systems Engineering Laboratory, Institute of Energy and Process Engineering, Department of Mechanical and Process Engineering, ETH Zurich CH-8092 Zurich Switzerland., Kubsch CMP; Particle Technology Laboratory, Institute of Energy and Process Engineering, Department of Mechanical and Process Engineering, ETH Zurich CH-8092 Zurich Switzerland pratsinis@ethz.ch., Pratsinis SE; Particle Technology Laboratory, Institute of Energy and Process Engineering, Department of Mechanical and Process Engineering, ETH Zurich CH-8092 Zurich Switzerland pratsinis@ethz.ch.
Jazyk: angličtina
Zdroj: Nanoscale advances [Nanoscale Adv] 2024 Jan 31; Vol. 6 (4), pp. 1259-1268. Date of Electronic Publication: 2024 Jan 31 (Print Publication: 2024).
DOI: 10.1039/d3na00558e
Abstrakt: Combustion aerosol processes can uniquely embed noble metals into semiconducting particles. Here, monocrystalline SnO 2 particles embedded with Pd and/or PdO x were made by flame spray pyrolysis (FSP) of appropriate precursors through microexplosions by droplet-to-particle conversion as the crystal size was proportional to the cube root of precursor solution concentration, C . These particles were air-annealed and leached with nitric acid for removal of metallic Pd from their surface. The SnO 2 crystal size varied from 11 to 24 nm and was in close agreement with the primary particle size determined by nitrogen adsorption. The embedded fraction of Pd ranged from about 30 to 80% of the nominal Pd-content. This was achieved by judiciously varying the C , Pd content and the ratio of precursor solution to dispersion oxygen flowrates during FSP. The response of sensors made by doctor blading films of such particles to 1 ppm of acetone and CO was evaluated at 350 °C and 50% relative humidity. Embedding Pd/PdO x into SnO 2 significantly increased the sensor response: 2-6 times over that of pure or conventionally-made Pd-containing SnO 2 sensors at low nominal Pd-contents (0.2 mol%). For higher ones ( i.e. 1 mol% Pd), the sensor response was enhanced by up to two orders of magnitude. This is attributed to Pd atoms in the SnO 2 lattice near the particle surface and/or Pd/PdO x clusters acting as nanoelectrodes into SnO 2 films and altering their transducing properties as shown by high resolution electron microscopy, XPS and baseline resistance measurements of pure and Pd-embedded SnO 2 sensing films.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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