Chiral versus Achiral Assemblies in Multi-Stimuli Responsive Supramolecular Polymerization of Tetra-Substituted Azobenzene Dye.

Autor: Čonková M; Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań, 61-614, Poland.; Center for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland., Markiewicz G; Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań, 61-614, Poland.; Center for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland., Majchrzycki Ł; Center for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland., Szmulewicz A; Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań, 61-614, Poland.; Center for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland., Stefankiewicz AR; Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, Poznań, 61-614, Poland.; Center for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, Poznań, 61-614, Poland.
Jazyk: angličtina
Zdroj: Small methods [Small Methods] 2024 Oct; Vol. 8 (10), pp. e2301681. Date of Electronic Publication: 2024 Feb 12.
DOI: 10.1002/smtd.202301681
Abstrakt: Incorporating photoswitchable moieties into the molecular design of supramolecular architectures provides unique opportunities for controlling their morphology and functionality via optical stimuli. Harnessing geometrical and electrical changes in response to multiple external stimuli on the molecular level to modulate properties remains a fundamental challenge. Herein, the reversible formation of the aggregates of l-tyrosine E-azobenzene-tetracarboxamide (E-ABT) is shown to be finely controlled by light, solvent, or chemical additives. The resulting products differ not only in their overall morphology and supramolecular interactions, but also in their intrinsic chirality, that is, depending on the conditions applied, self-assembly yields chiral columns or π-stacked "achiral" oligomers. This report shows the potential of rational monomer design to achieve controlled self-assembly by stimuli of choice and paves the way toward the use of multi-responsive, sterically hindered azo-benzene aggregates in materials chemistry and nanotechnology.
(© 2024 The Authors. Small Methods published by Wiley‐VCH GmbH.)
Databáze: MEDLINE
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