| Autor: |
Haworth AR; Department of Chemistry, Lancaster University, Lancaster LA1 4YB, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Johnston BIJ; Department of Materials Science and Engineering, University of Sheffield, Sheffield S1 3JD, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Wheatcroft L; Department of Materials Science and Engineering, University of Sheffield, Sheffield S1 3JD, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., McKinney SL; Department of Chemistry, Lancaster University, Lancaster LA1 4YB, U.K.; Department of Chemistry, Molecular Sciences Research Hub, White City Campus, Imperial College London, London W12 0BZ, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Tapia-Ruiz N; Department of Chemistry, Molecular Sciences Research Hub, White City Campus, Imperial College London, London W12 0BZ, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Booth SG; Department of Materials Science and Engineering, University of Sheffield, Sheffield S1 3JD, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Nedoma AJ; Department of Chemical and Biological Engineering, University of Sheffield, Sheffield S1 3JD, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Cussen SA; Department of Materials Science and Engineering, University of Sheffield, Sheffield S1 3JD, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K., Griffin JM; Department of Chemistry, Lancaster University, Lancaster LA1 4YB, U.K.; The Faraday Institution, Quad One, Harwell Campus, Didcot OX11 0RA, U.K. |
| Abstrakt: |
Layered transition metal oxide cathode materials can exhibit high energy densities in Li-ion batteries, in particular, those with high Ni contents such as LiNiO 2 . However, the stability of these Ni-rich materials often decreases with increased nickel content, leading to capacity fade and a decrease in the resulting electrochemical performance. Thin alumina coatings have the potential to improve the longevity of LiNiO 2 cathodes by providing a protective interface to stabilize the cathode surface. The structures of alumina coatings and the chemistry of the coating-cathode interface are not fully understood and remain the subject of investigation. Greater structural understanding could help to minimize excess coating, maximize conductive pathways, and maintain high capacity and rate capability while improving capacity retention. Here, solid-state nuclear magnetic resonance (NMR) spectroscopy, paired with powder X-ray diffraction and electron microscopy, is used to provide insight into the structures of the Al 2 O 3 coatings on LiNiO 2 . To do this, we performed a systematic study as a function of coating thickness and used LiCoO 2 , a diamagnetic model, and the material of interest, LiNiO 2 . 27 Al magic-angle spinning (MAS) NMR spectra acquired for thick 10 wt % coatings on LiCoO 2 and LiNiO 2 suggest that in both cases, the coatings consist of disordered four- and six-coordinate Al-O environments. However, 27 Al MAS NMR spectra acquired for thinner 0.2 wt % coatings on LiCoO 2 identify additional phases believed to be LiCo 1- x Al x O 2 and LiAlO 2 at the coating-cathode interface. 6,7 Li MAS NMR and T 1 measurements suggest that similar mixing takes place near the interface for Al 2 O 3 on LiNiO 2 . Furthermore, reproducibility studies have been undertaken to investigate the effect of the coating method on the local structure, as well as the role of the substrate. |
