| Autor: |
Denikaev A; Ural Federal University, 19 Mira St., 620002 Ekaterinburg, Russia., Kuznetsova Y; Institute of Solid State Chemistry of the Ural Branch of the RAS, 91, Pervomaiskaya St., 620990 Ekaterinburg, Russia., Bykov A; Institute of Chemistry, St. Petersburg State University, Universitetsky pr. 26, 198504 St. Petersburg, Russia., Zhilyakov A; Ural Federal University, 19 Mira St., 620002 Ekaterinburg, Russia.; M.N. Mikheev lnstitute of Metal Physics of Ural Branch of RAS,18 S. Kovalevskaya St., 620108 Ekaterinburg, Russia., Belova K; Ural Federal University, 19 Mira St., 620002 Ekaterinburg, Russia.; Institute of High Temperature Electrochemistry of the Ural Branch of RAS, 22 S. Kovalevskoy St./20 Akademicheskaya St., 620066 Ekaterinburg, Russia., Abramov P; Ural Federal University, 19 Mira St., 620002 Ekaterinburg, Russia.; Nikolaev Institute of Inorganic Chemistry Siberian Branch of RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia., Moskalenko N; Institute of High Temperature Electrochemistry of the Ural Branch of RAS, 22 S. Kovalevskoy St./20 Akademicheskaya St., 620066 Ekaterinburg, Russia., Skorb E; Infochemistry Scientific Center, ITMO University, Kronverksky Pr. 49, bldg. A, 197101 St. Petersburg, Russia., Grzhegorzhevskii K; Ural Federal University, 19 Mira St., 620002 Ekaterinburg, Russia. |
| Abstrakt: |
Self-assembly gives rise to the versatile strategies of smart material design but requires precise control on the supramolecular level. Here, inorganic-organic synthons (conjugates) are produced by covalently grafting stearic acid tails to giant polyoxometalate (POM) Keplerate-type {Mo 132 } through an organosilicon linker (3-aminopropyltrimethoxysilane, APTMS). Using the liposome production approach, the synthons self-assemble to form hollow nanosized vesicles (100-200 nm in diameter), which can be loaded with organic dyes─eriochrome black T (ErChB) and fluorescein (FL)─where the POM layer serves as a membrane with subnanopores for cell-like communication. The dye structure plays an essential role in embedding dyes into the vesicle's shell, which opens the way to control the colloidal stability of the system. The produced vesicles are moved by an electric field and used for the creation of an infochemistry scheme with three types of logic gates (AND, OR, and IMP). To design 2D materials, synthons can form spread films, from simple addition on the water-air interface to lateral compression in the Langmuir bath, and highly ordered structures appear, demonstrating electron diffraction in Langmuir-Schaefer (LS) films. These results show the significant potential of POM-based synthons and nanosized vesicles to supramolecular design the diversity of smart materials. |
