| Autor: |
Chikaoka Y; Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8558, Japan. chika@go.tuat.ac.jp.; Global Innovation Research Organization, Tokyo University of Agriculture & Technology, 2-24-16 Naka-cho, Koganei, Tokyo, 184-8588, Japan., Tashiro T; Graduate School of Sciences and Technology for Innovation, Yamaguchi University, 2-16-1 Tokiwadai, Ube, Yamaguchi 755-8611, Japan. k-fujii@yamaguchi-u.ac.jp., Sawayama S; Graduate School of Sciences and Technology for Innovation, Yamaguchi University, 2-16-1 Tokiwadai, Ube, Yamaguchi 755-8611, Japan. k-fujii@yamaguchi-u.ac.jp., Kobayashi A; Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8558, Japan. chika@go.tuat.ac.jp., Matsumoto A; Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8558, Japan. chika@go.tuat.ac.jp., Iwama E; Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8558, Japan. chika@go.tuat.ac.jp.; Global Innovation Research Organization, Tokyo University of Agriculture & Technology, 2-24-16 Naka-cho, Koganei, Tokyo, 184-8588, Japan., Naoi K; Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8558, Japan. chika@go.tuat.ac.jp.; Global Innovation Research Organization, Tokyo University of Agriculture & Technology, 2-24-16 Naka-cho, Koganei, Tokyo, 184-8588, Japan., Fujii K; Graduate School of Sciences and Technology for Innovation, Yamaguchi University, 2-16-1 Tokiwadai, Ube, Yamaguchi 755-8611, Japan. k-fujii@yamaguchi-u.ac.jp. |
| Abstrakt: |
Dimethyl carbonate (DMC) is a linear carbonate solvent commonly used as an electrolyte for electric double-layer capacitors (EDLCs) and Li-ion batteries. However, there are serious problems with the use of DMC as an electrolyte solvent: (1) low ionic conductivity when using Li salts ( e.g. LiBF 4 ) and (2) liquid-liquid phase separation when using spiro-type quaternary ammonium salts ( e.g. SBPBF 4 ). Dual-cation electrolytes, i.e. , bi-salt (SBPBF 4 and LiBF 4 ) in DMC, are promising candidates to avoid the phase separation issue and to enhance the total and Li + conductivities. Herein, we reported a specific Li-ion structure in DMC-based dual-cation electrolytes by combining high-energy X-ray total scattering (HEXTS) and all-atom molecular dynamics (MD) simulations. Quantitative radial distribution function analysis based on experimental and simulation results revealed that the phase-separated SBPBF 4 /DMC ( i.e. , the bottom phase of 1 M SBPBF 4 /DMC) forms long-range ion ordering based on the structured SBP + -BF 4 - ion pairs. When adding LiBF 4 salt into SBPBF 4 /DMC ( i.e. , dual-cation electrolyte), the ordered SBP + -BF 4 - structure disappeared owing to the formation of Li-ion solvation complexes. We found that in the dual-cation electrolyte Li ions form multiple Li + -Li + ordered complexes in spite of relatively low Li-salt concentration (1 M), being a promising Li + -conducting medium with reduced Li salt usage and low viscosity. |
