Exploring Non-Toxic Lower Dimensional Perovskites for Next-Generation X-Ray Detectors.

Autor: Ali N; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China., Shehzad K; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China., Attique S; State Key Laboratory of Extreme Photonics and Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China., Ali A; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China., Akram F; Center for High Technology Materials and the Department of Mechanical Engineering, The University of New Mexico, Albuquerque, NM, 87131, USA., Younis A; Department of Physics, College of Science, United Arab Emirates University, Al-Ain, 15551, United Arab Emirates., Ali S; Department of Physics, University of Peshawar, Peshawar, 25000, Pakistan., Sun Y; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China., Yu G; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China., Wu H; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China.; School of Physics, State Key Laboratory for Silicon Materials, Zhejiang University, Hangzhou, 310027, P. R. China., Dai N; Research Center for Frontier Fundamental Studies, Zhejiang Labs, Yuhang District, Hangzhou, Zhejiang, 311121, P. R. China.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2024 Jun; Vol. 20 (23), pp. e2310946. Date of Electronic Publication: 2024 Jan 17.
DOI: 10.1002/smll.202310946
Abstrakt: Owing to their extraordinary photophysical properties, organometal halide perovskites are emerging as a new material class for X-ray detection. However, the existence of toxic lead makes their commercialization questionable and should readily be replaced. Accordingly, several lead alternatives have been introduced into the framework of conventional perovskites, resulting in various new perovskite dimensionalities. Among these, Pb-free lower dimensional perovskites (LPVKs) not only show promising X-ray detecting properties due to their higher ionic migration energy, wider and tunable energy bandgap, smaller dark currents, and structural versatility but also exhibit extended environmental stability. Herein, first, the structural organization of the PVKs (including LPVKs) is summarized. In the context of X-ray detectors (XDs), the outstanding properties of the LPVKs and active layer synthesis routes are elaborated afterward. Subsequently, their applications in direct XDs are extensively discussed and the device performance, in terms of the synthesis method, device architecture, active layer size, figure of merits, and device stability are tabulated. Finally, the review is concluded with an in-depth outlook, thoroughly exploring the present challenges to LPVKs XDs, proposing innovative solutions, and future directions. This review provides valuable insights into optimizing non-toxic Pb-free perovskite XDs, paving the way for future advancements in the field.
(© 2024 Wiley‐VCH GmbH.)
Databáze: MEDLINE
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