Facile synthesis of hydroxylated triazine-based magnetic microporous organic network for ultrahigh adsorption of phenylurea herbicides: An experimental and density-functional theory study.

Autor: Liu L; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China., Qiao LQ; College of Plant Protection, Shandong Agricultural University, Taian 271018, China. Electronic address: lqqiao@sdau.edu.cn., Liu F; Quality department, Sinotruk Jinan Truck Co., Ltd., Jinan 250000, China., Sun QY; Shandong Institute of Metrology, Jinan 250014, China., Zhao YF; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China., Wang XL; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China., Li N; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China., Jiang HL; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China., Chen XF; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China., Wang ML; College of Food Science and Engineering, Shandong Agricultural University, Taian 271018, China., Wu YN; China National Centre for Food Safety Risk Assessment, Beijing 100022, China., Zhao RS; Qilu University of Technology (Shandong Academy of Sciences), Shandong Analysis and Test Center, Jinan 250014, China. Electronic address: zhaors1976@126.com.
Jazyk: angličtina
Zdroj: Journal of hazardous materials [J Hazard Mater] 2024 Mar 05; Vol. 465, pp. 133468. Date of Electronic Publication: 2024 Jan 10.
DOI: 10.1016/j.jhazmat.2024.133468
Abstrakt: Microporous organic networks (MONs) are highly porous materials that are particularly useful in analytical chemistry. However, the use of these materials is often limited by the functional groups available on their surface. Here, we described the polymerization of a sea urchin-like structure material at ambient temperature, that was functionalized with hydroxyl, carboxyl, and triazine groups and denoted as OH-COOH-MON-TEPT. A substantial proportion of OH-COOH-MON-TEPT was intricately decorated EDA-Fe 3 O 4 , creating a well-designed configuration (EDA-Fe 3 O 4 @OH-COOH-MON-TEPT-EDC) for superior adsorption of the target analytes phenylurea herbicides (PUHs) via magnetic solid-phase extraction (MSPE). The proposed method showed remarkably low limits of detection ranging from 0.03 to 0.22 ng·L -1 . Experimental investigations and theoretical analyses unveiled the adsorption mode between EDA-Fe 3 O 4 @OH-COOH-MON-TEPT-EDC and PUHs. These findings establish a robust foundation for potential applications of EDA-Fe 3 O 4 @OH-COOH-MON-TEPT-EDC in the analysis of various polar contaminants.
Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2024 Elsevier B.V. All rights reserved.)
Databáze: MEDLINE
Externí odkaz: