| Autor: |
Szatkowski P; Department of Biomaterials and Composites, Faculty of Materials Science and Ceramics, AGH University of Krakow, Al. Mickiewicza 30, 30-059 Krakow, Poland., Gralewski J; Institute of Marketing and Sustainable Development, Lodz University of Technology, 93-590 Lodz, Poland., Suchorowiec K; Department of Biomaterials and Composites, Faculty of Materials Science and Ceramics, AGH University of Krakow, Al. Mickiewicza 30, 30-059 Krakow, Poland., Kosowska K; Solaris National Synchrotron Radiation Centre, Jagiellonian University, Czerwone Maki 98, 30-392 Krakow, Poland., Mielan B; Pre-Clinical Research Centre, Wroclaw Medical University, Bujwida 44, 50-345 Wroclaw, Poland., Kisilewicz M; Technology Transfer Center, University of Applied Sciences in Tarnow, Ul. Mickiewicza 8, 33-100 Tarnow, Poland. |
| Abstrakt: |
In the modern world, many products are disposable or have a very short lifespan, while at the same time, those products are made from materials that will remain in the environment in the form of waste for hundreds or even thousands of years. It is a serious problem; non-biodegradable polymer wastes are part of environmental pollution and generate microplastics, which accumulate in the organisms of living beings. One of the proposed solutions is biodegradable polymers and their composites. In our work, three types of polylactide-based composites with plant-derived fillers: microcellulose powder, short flax fibers, and wood flour at 2 wt.% were prepared. Poly(lactic acid) (PLA)-based biocomposite properties were characterized in terms of mechanical and surface properties together with microscopic analysis and Fourier-transform infrared spectroscopy (FTIR), before and after a UV (ultraviolet)-light-aging process to determine the effects of each cellulose-based additive on the UV-induced degradation process. This research shows that the addition of a cellulose additive can improve the properties of the material in terms of the UV-aging process, but the form of the chosen cellulose form plays a crucial role in this case. The testing of physicochemical properties demonstrated that not only can mechanical properties be improved, but also the time of degradation under UV light exposure can be controlled by the proper selection of the reinforcing phase and the parameters of the extrusion and injection molding process. The obtained results turned out to be very interesting, not only in terms of the cost reduction of the biocomposites themselves, as mainly the waste from the wood industry was used as a low-cost filler, but also that the additive delays the aging process occurring during UV light exposure. Even a small, 2 wt.% addition of some of the tested forms of cellulose delayed surface degradation, which is one of the most important factors affecting the biodegradation process. |
