Calcium ferrites for phosphate adsorption and recovery from wastewater.

Autor: Araújo MHP; Universidade Federal de Viçosa - Campus Florestal - UFV Rodovia LMG 818, km 06, s/n, Campus Universitário Florestal MG 35690-000 Brazil matheus.pimentel@ufv.br., Ardisson JD; Centro de Desenvolvimento da Tecnologia Nuclear - CDTN/CNEN, campus da Universidade Federal de Minas Gerais Avenida Presidente Antônio Carlos, No 6627, Rua Mário Werneck, S/N - Pampulha Belo Horizonte MG Brazil., Krohling AC; Centro de Desenvolvimento da Tecnologia Nuclear - CDTN/CNEN, campus da Universidade Federal de Minas Gerais Avenida Presidente Antônio Carlos, No 6627, Rua Mário Werneck, S/N - Pampulha Belo Horizonte MG Brazil., Lago RM; Universidade Federal de Minas Gerais - UFMG Avenida Presidente Antônio Carlos, No 6627, Rua Mário Werneck, 2 - Pampulha Belo Horizonte MG 31270-901 Brazil., Guimarães Júnior W; Universidade Federal de São Carlos - UFSCar Rodovia Washington Luís, s/n - Monjolinho São Carlos - SP 13565-905 Brazil., Tristão JC; Universidade Federal de Viçosa - Campus Florestal - UFV Rodovia LMG 818, km 06, s/n, Campus Universitário Florestal MG 35690-000 Brazil matheus.pimentel@ufv.br.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2024 Jan 04; Vol. 14 (3), pp. 1612-1624. Date of Electronic Publication: 2024 Jan 04 (Print Publication: 2024).
DOI: 10.1039/d3ra05871a
Abstrakt: In this study, calcium ferrites with different Ca : Fe atomic ratios (1 : 1, 1 : 2, 1 : 3 and 2 : 1) were prepared from Ca and Fe nitrates treated at 300, 700 and 900 °C and evaluated for phosphate adsorption and recovery from wastewater. TG, XRD, Mössbauer spectroscopy, SEM, VSM magnetic measurements, and BET analyses showed the formation of two different calcium ferrite phases, i.e. , CaFe 2 O 4 and Ca 2 Fe 2 O 5 at 700 and 900 °C. The adsorption results indicated that the formation of calcium ferrite structure is critical for phosphate adsorption/recovery. Evaluation of the pH, initial phosphate concentration, contact time, coexisting ions and desorption conditions showed remarkable adsorption capacities of 62-75 mg g -1 for CaFe1:2-700 and 28-43 mg g -1 for CaFe1:2-900. The phosphate adsorption on the Ca ferrite surfaces is so strong that the recovery/desorption showed limited efficiencies, e.g. , 15-39%.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE