| Autor: |
Brotsman VA; Chemistry Department, Moscow State University, Leninskie gory, 119991 Moscow, Russia. brotsman_va@mail.ru., Troyanov SI; Chemistry Department, Moscow State University, Leninskie gory, 119991 Moscow, Russia. brotsman_va@mail.ru. |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jan 18; Vol. 60 (7), pp. 893-896. Date of Electronic Publication: 2024 Jan 18. |
| DOI: |
10.1039/d3cc05336a |
| Abstrakt: |
High-temperature chlorination of C 76 fullerene with SbCl 5 proceeds via five Stone-Wales rearrangements, resulting in non-classical (NC) C 76 (NC1a)Cl 24 with two heptagons and 14 pentagons partically fused in pairs and triples. C 76 (NC2b)Cl 28 with isomeric carbon cage was obtained by chlorination-promoted cage shrinkage of C 80 via two C 2 losses. The pathways of skeletal cage trasformations, the chlorination patterns, and formation energies are discussed in detail. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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