Nanomaterial grafted polymorphous activated carbon cloth surface for antibacterial, capacitive deionization and oil spill cleaning applications.

Autor: Kyaw HH; Nanotechnology Research Center, Sultan Qaboos University, PO Box 33, Al-Khoudh, 123, Muscat, Oman., Myint MTZ; Department of Physics, College of Science, Sultan Qaboos University, PO Box 36, Al-Khoudh, 123, Muscat, Oman. Electronic address: myomyint@squ.edu.om., Al-Belushi MA; Department of Marine Science and Fisheries, College of Agriculture and Marine Sciences, Sultan Qaboos University, PO Box 34, Al-Khoudh, 123, Muscat, Oman; Central Laboratory for Food Safety, Food Safety and Quality Center, Ministry of Agriculture, Fisheries Wealth & Water Resources, PO Box 3094, Airport Central Post,111, Muscat, Oman., Dobretsov S; Department of Marine Science and Fisheries, College of Agriculture and Marine Sciences, Sultan Qaboos University, PO Box 34, Al-Khoudh, 123, Muscat, Oman., Al-Abri M; Nanotechnology Research Center, Sultan Qaboos University, PO Box 33, Al-Khoudh, 123, Muscat, Oman; Department of Petroleum and Chemical Engineering, College of Engineering, Sultan Qaboos University, PO Box 33, Al-Khoudh, 123, Muscat, Oman. Electronic address: alabri@squ.edu.om.
Jazyk: angličtina
Zdroj: Chemosphere [Chemosphere] 2024 Feb; Vol. 350, pp. 141053. Date of Electronic Publication: 2023 Dec 26.
DOI: 10.1016/j.chemosphere.2023.141053
Abstrakt: This work reports the development of multifunctional or polymorphous surfaces using zinc oxide (ZnO) nanorods, silica (SiO 2 ), and fluoropolymer functionalization in a sequential process. Firstly, zinc oxide nanorods were grown on activated carbon cloth (ACC) using a simple low-temperature synthesis process. ZnO nanorods-coated ACC substrate was applied to investigate the antimicrobial properties, and the results showed inhibition of 50% for Escherichia coli (E.coli) and 55% for Bacillus subtilis (B.subtilis) over 48 h of incubation time. Subsequent in-situ modification of silica nanoparticles like layer on ZnO nanorods-coated ACC surface was developed and used as an electrode for brackish water desalination in a capacitive deionization system. ZnO-SiO 2 modified ACC surface enhanced the desalination efficiency by 1.6 times, the salt removal rate (SRR) by threefold, and the durability (fouling prevention) for long-term usage compared to pristine ACC. Further modification of the ZnO-SiO 2 -ACC surface using fluoropolymer rendered the surface superhydrophobic and oleophilic. Vegetable (1.4 g/g) and crude oil (1.6 g/g) adsorption capacities were achieved for modified surface which was 70% enhancement compared with pristine ACC. The dynamic oil spill adsorption test exhibited the complete removal of oil spills on water surfaces within a few seconds, suggesting a potential application in oil spill cleaning.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2023 Elsevier Ltd. All rights reserved.)
Databáze: MEDLINE