| Autor: |
Konkova AV; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia., Savina IV; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia., Evtushok DV; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia., Pozmogova TN; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia., Solomatina MV; Research Institute of Virology, Federal Research Center of Fundamental and Translational Medicine, 2 Timakova St, Novosibirsk 630117, Russia., Nokhova AR; Research Institute of Virology, Federal Research Center of Fundamental and Translational Medicine, 2 Timakova St, Novosibirsk 630117, Russia., Alekseev AY; Research Institute of Virology, Federal Research Center of Fundamental and Translational Medicine, 2 Timakova St, Novosibirsk 630117, Russia.; Research Institute of Applied Ecology, Dagestan State University, 43a Gadzhiyeva St, Makhachkala 367000, Russia., Kuratieva NV; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia., Eltsov IV; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk 630090, Russia., Yanshole VV; International Tomography Center SB RAS, 3a Institutskaya Str., Novosibirsk 630090, Russia.; Department of Physics, Novosibirsk State University, 1 Pirogova St., Novosibirsk 630090, Russia., Shestopalov AM; Research Institute of Virology, Federal Research Center of Fundamental and Translational Medicine, 2 Timakova St, Novosibirsk 630117, Russia.; Research Institute of Applied Ecology, Dagestan State University, 43a Gadzhiyeva St, Makhachkala 367000, Russia., Ivanov AA; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia., Shestopalov MA; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia. |
| Abstrakt: |
Among well-studied and actively developing compounds are polyoxometalates (POMs), which show application in many fields. Extending this class of compounds, we introduce a new subclass of polyoxometal clusters (POMCs) [Mo 12 O 28 (μ-L) 8 ] 4- (L = pyrazolate (pz) or triazolate (1,2,3-trz or 1,2,4-trz)), structurally similar to POM, but containing binuclear Mo 2 O 4 clusters linked by bridging oxo- and organic ligands. The complexes obtained by ampoule synthesis from the binuclear cluster [Mo 2 O 4 (C 2 O 4 ) 2 (H 2 O) 2 ] 2- in a melt of an organic ligand are soluble and stable in aqueous solutions. In addition to the detailed characterization in solid state and in aqueous solution, the biological properties of the compounds on normal and cancer cells were investigated, and antiviral activity against influenza A virus (subtype H5N1) was demonstrated. |
