Metal-Organic Framework (MOF)-Based Clean Energy Conversion: Recent Advances in Unlocking its Underlying Mechanisms.

Autor: Zhu Z; Key Laboratory for Soft Chemistry and Functional Materials, School of Chemistry and Chemical Engineering, School of Energy and Power Engineering, Nanjing University of Science and Technology, Ministry of Education, Nanjing, 210094, China., Duan J; Key Laboratory for Soft Chemistry and Functional Materials, School of Chemistry and Chemical Engineering, School of Energy and Power Engineering, Nanjing University of Science and Technology, Ministry of Education, Nanjing, 210094, China., Chen S; Key Laboratory for Soft Chemistry and Functional Materials, School of Chemistry and Chemical Engineering, School of Energy and Power Engineering, Nanjing University of Science and Technology, Ministry of Education, Nanjing, 210094, China.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2024 May; Vol. 20 (20), pp. e2309119. Date of Electronic Publication: 2023 Dec 21.
DOI: 10.1002/smll.202309119
Abstrakt: Carbon neutrality is an important goal for humanity . As an eco-friendly technology, electrocatalytic clean energy conversion technology has emerged in the 21st century. Currently, metal-organic framework (MOF)-based electrocatalysis, including oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), hydrogen oxidation reaction (HOR), carbon dioxide reduction reaction (CO 2 RR), nitrogen reduction reaction (NRR), are the mainstream energy catalytic reactions, which are driven by electrocatalysis. In this paper, the current advanced characterizations for the analyses of MOF-based electrocatalytic energy reactions have been described in details, such as density function theory (DFT), machine learning, operando/in situ characterization, which provide in-depth analyses of the reaction mechanisms related to the above reactions reported in the past years. The practical applications that have been developed for some of the responses that are of application values, such as fuel cells, metal-air batteries, and water splitting have also been demonstrated. This paper aims to maximize the potential of MOF-based electrocatalysts in the field of energy catalysis, and to shed light on the development of current intense energy situations.
(© 2023 Wiley‐VCH GmbH.)
Databáze: MEDLINE
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