Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems.

Autor: Lachguar A; Université de Lyon, Institut de Chimie de Lyon, Laboratory of Catalysis, Polymerization, Processes & Materials, CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon, 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne, France. clement.camp@univ-lyon1.fr., Pichugov AV; Université de Lyon, Institut de Chimie de Lyon, Laboratory of Catalysis, Polymerization, Processes & Materials, CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon, 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne, France. clement.camp@univ-lyon1.fr., Neumann T; Université de Lyon, Institut de Chimie de Lyon, Laboratory of Catalysis, Polymerization, Processes & Materials, CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon, 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne, France. clement.camp@univ-lyon1.fr., Dubrawski Z; Université de Lyon, Institut de Chimie de Lyon, Laboratory of Catalysis, Polymerization, Processes & Materials, CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon, 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne, France. clement.camp@univ-lyon1.fr., Camp C; Université de Lyon, Institut de Chimie de Lyon, Laboratory of Catalysis, Polymerization, Processes & Materials, CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon, 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne, France. clement.camp@univ-lyon1.fr.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2024 Jan 23; Vol. 53 (4), pp. 1393-1409. Date of Electronic Publication: 2024 Jan 23.
DOI: 10.1039/d3dt03571a
Abstrakt: The direct activation of C-H bonds has been a rich and active field of organometallic chemistry for many years. Recently, incredible progress has been made and important mechanistic insights have accelerated research. In particular, the use of heterobimetallic complexes to heterolytically activate C-H bonds across the two metal centers has seen a recent surge in interest. This perspective article aims to orient the reader in this fast moving field, highlight recent progress, give design considerations for further research and provide an optimistic outlook on the future of catalytic C-H functionalization with heterobimetallic complexes.
Databáze: MEDLINE
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