Lead-free organic-inorganic azetidinium alternating metal cation bromide: [(CH 2 ) 3 NH 2 ] 2 AgBiBr 6 , a perovskite-related absorber.

Autor: Jin YU; Institute for Materials Science, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen 45141 Essen Germany doru.lupascu@uni-due.de., Marler B; Institute of Geology, Mineralogy and Geophysics, Ruhr-University Bochum 44780 Bochum Germany., Karabanov AD; Institute for Materials Science, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen 45141 Essen Germany doru.lupascu@uni-due.de., Winkler K; Institute of Technology for Nanostructures (NST), University of Duisburg-Essen 47057 Duisburg Germany.; Fraunhofer Institute for Solar Energy Systems (ISE) 79110 Freiburg Germany., Yap ICJ; Institute for Materials Science, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen 45141 Essen Germany doru.lupascu@uni-due.de., Dubey A; Institute for Materials Science, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen 45141 Essen Germany doru.lupascu@uni-due.de., Spee L; Electroenergetic Functional Materials (EEFM), CENIDE, University Duisburg-Essen 47057 Duisburg Germany.; Werkstoffe der Elektrotechnik (WET), CENIDE, University Duisburg-Essen 47057 Duisburg Germany., Escobar Castillo M; Institute for Materials Science, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen 45141 Essen Germany doru.lupascu@uni-due.de., Muckel F; Electroenergetic Functional Materials (EEFM), CENIDE, University Duisburg-Essen 47057 Duisburg Germany., Salak AN; Department of Materials and Ceramics Engineering, CICECO-Aveiro Institute of Materials, University of Aveiro 3810-193 Aveiro Portugal., Benson N; Institute of Technology for Nanostructures (NST), University of Duisburg-Essen 47057 Duisburg Germany., Lupascu DC; Institute for Materials Science, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen 45141 Essen Germany doru.lupascu@uni-due.de.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2023 Dec 12; Vol. 13 (51), pp. 36079-36087. Date of Electronic Publication: 2023 Dec 12 (Print Publication: 2023).
DOI: 10.1039/d3ra05966a
Abstrakt: In the last decade, organic-inorganic hybrid halide perovskite materials have developed into a very large research area in photovoltaics and optoelectronics as promising light harvesters. Lead-free double perovskites have recently been investigated as an environmentally friendly alternative to the lead-containing compositions. However, lead-free organic-inorganic hybrid halide double perovskites have so far rarely been produced due to a certain complexity in their synthesis. A number of small molecular cations have been investigated, but compositions containing azetidinium, which is a 4-membered heterocyclic molecular ring, on the A-site have hardly been considered. This study investigates the potential of [(CH 2 ) 3 NH 2 ] 2 AgBiBr 6 as an optical absorber in photovoltaics or optoelectronics. The use of this alternative cation changes the crystal symmetry significantly. Columns of alternating metal cation form which are separated by the organic ions. While crystal symmetry is rather different from the perovskites, the overall properties as an absorber are similar. It is thus worthwhile to further investigate alternate hybrid compositions which form into other symmetries than the perovskite base structure.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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