| Autor: |
Mutovska M; Faculty of Chemistry and Pharmacy, Sofia University 'St. Kliment Ohridski', 1164 Sofia, Bulgaria., Simeonova N; Faculty of Chemistry and Pharmacy, Sofia University 'St. Kliment Ohridski', 1164 Sofia, Bulgaria., Stoyanov S; Faculty of Chemistry and Pharmacy, Sofia University 'St. Kliment Ohridski', 1164 Sofia, Bulgaria., Zagranyarski Y; Faculty of Chemistry and Pharmacy, Sofia University 'St. Kliment Ohridski', 1164 Sofia, Bulgaria., Stanchovska S; Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria., Marinova D; Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria. |
| Jazyk: |
angličtina |
| Zdroj: |
Materials (Basel, Switzerland) [Materials (Basel)] 2023 Dec 01; Vol. 16 (23). Date of Electronic Publication: 2023 Dec 01. |
| DOI: |
10.3390/ma16237471 |
| Abstrakt: |
Nowadays, organosulfur compounds provide new options in the development of full organic ion batteries. However, many drawbacks (such as kinetics limitations during the reversible oxidation of disulfides with cleavage of S-S bond, as well as solubility in non-aqueous electrolytes) make their commercialization difficult. Herein, a new concept for the design of organosulfur compounds with regulated redox properties and limited solubility is proposed. As a proof-of-concept, we designed peri -disulfo-substituted 1,8-naphthalimide derivatives, in which the alkyl chain length and halogen substituents (Cl or Br) at positions 3 and 6 are varied. The compounds were synthesized by an originally developed procedure starting from tetrahalonaphthalic anhydride via nucleophilic substitution at both peri -positions in the respective imide. Using ionic liquid electrolyte, it was found that the new peri -dithiolo-1,8-naphthalimides can participate in n - and p -type redox reactions at about 2.0 V and above 4.0 V vs. Li/Li + , respectively. The redox potentials are sensitive mainly to whether Cl or Br substituents are available in the molecule architecture, while the alkyl chain length determines the kinetics of the redox reactions. Among all compounds, the chloro-substituted compound with the shorter alkyl chain displays the best kinetics for both low- and high-voltage redox reactions. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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