Expanding the horizons of porphyrin metal-organic frameworks via catecholate coordination: exploring structural diversity, material stability and redox properties.

Autor: De S; Laboratoire des Multimatériaux et Interfaces, Université Lyon, Université Claude Bernard Lyon 1, UMR CNRS 5615 F-69622 Villeurbanne France alexandra.fateeva@univ-lyon1.fr., Mouchaham G; Institut Lavoisier de Versailles, UMR 8180 CNRS UVSQ, Université Paris-Saclay 45 Avenue des Etats-Unis 78035 Versailles France., Liu F; Laboratoire des Multimatériaux et Interfaces, Université Lyon, Université Claude Bernard Lyon 1, UMR CNRS 5615 F-69622 Villeurbanne France alexandra.fateeva@univ-lyon1.fr., Affram M; Institut Lavoisier de Versailles, UMR 8180 CNRS UVSQ, Université Paris-Saclay 45 Avenue des Etats-Unis 78035 Versailles France., Abeykoon B; Laboratoire des Multimatériaux et Interfaces, Université Lyon, Université Claude Bernard Lyon 1, UMR CNRS 5615 F-69622 Villeurbanne France alexandra.fateeva@univ-lyon1.fr., Guillou N; Institut Lavoisier de Versailles, UMR 8180 CNRS UVSQ, Université Paris-Saclay 45 Avenue des Etats-Unis 78035 Versailles France., Jeanneau E; Laboratoire des Multimatériaux et Interfaces, Université Lyon, Université Claude Bernard Lyon 1, UMR CNRS 5615 F-69622 Villeurbanne France alexandra.fateeva@univ-lyon1.fr., Grenèche JM; Institut des Molécules et Matériaux du Mans, IMMM UMR CNRS 6283, Le Mans Université Le Mans Cedex 9 F-72085 France., Khrouz L; ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182 F-69342 Lyon France., Martineau-Corcos C; Institut Lavoisier de Versailles, UMR 8180 CNRS UVSQ, Université Paris-Saclay 45 Avenue des Etats-Unis 78035 Versailles France., Boudjema L; ICGM, Univ. Montpellier, CNRS, ENSCM Montpellier France., Salles F; ICGM, Univ. Montpellier, CNRS, ENSCM Montpellier France., Salcedo-Abraira P; Nantes Université, CNRS, Institut des Matériaux de Nantes Jean Rouxel, IMN F-44000 Nantes France thomas.devic@cnrs-imn.fr., Valente G; Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro Aveiro 3810-393 Portugal., Souto M; Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro Aveiro 3810-393 Portugal., Fateeva A; Laboratoire des Multimatériaux et Interfaces, Université Lyon, Université Claude Bernard Lyon 1, UMR CNRS 5615 F-69622 Villeurbanne France alexandra.fateeva@univ-lyon1.fr., Devic T; Nantes Université, CNRS, Institut des Matériaux de Nantes Jean Rouxel, IMN F-44000 Nantes France thomas.devic@cnrs-imn.fr.
Jazyk: angličtina
Zdroj: Journal of materials chemistry. A [J Mater Chem A Mater] 2023 Nov 03; Vol. 11 (46), pp. 25465-25483. Date of Electronic Publication: 2023 Nov 03 (Print Publication: 2023).
DOI: 10.1039/d3ta04490d
Abstrakt: Porphyrin based Metal-Organic Frameworks (MOFs) have generated high interest because of their unique combination of light absorption, electron transfer and guest adsorption/desorption properties. In this study, we expand the range of available MOF materials by focusing on the seldom studied porphyrin ligand H 10 TcatPP, functionalized with tetracatecholate coordinating groups. A systematic evaluation of its reactivity with M(iii) cations (Al, Fe, and In) led to the synthesis and isolation of three novel MOF phases. Through a comprehensive characterization approach involving single crystal and powder synchrotron X-ray diffraction (XRD) in combination with the local information gained from spectroscopic techniques, we elucidated the structural features of the solids, which are all based on different inorganic secondary building units (SBUs). All the synthesized MOFs demonstrate an accessible porosity, with one of them presenting mesopores and the highest reported surface area to date for a porphyrin catecholate MOF (>2000 m 2 g -1 ). Eventually, the redox activity of these solids was investigated in a half-cell vs. Li with the aim of evaluating their potential as electrode positive materials for electrochemical energy storage. One of the solids displayed reversibility during cycling at a rather high potential (∼3.4 V vs. Li + /Li), confirming the interest of redox active phenolate ligands for applications involving electron transfer. Our findings expand the library of porphyrin-based MOFs and highlight the potential of phenolate ligands for advancing the field of MOFs for energy storage materials.
Competing Interests: There are no conflicts of interest to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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