Light-Mediated Polymerization Catalyzed by Carbon Nanomaterials.

Autor: Luo X; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China.; Northeast Forestry University, College of Chemistry, Chemical Engineering and Resource Utilization, Hexing Road 26, Harbin, 150040, China., Zhai Y; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China., Wang P; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China.; Niederrhein University of Applied Sciences, Department of Chemistry, Institute for Coatings and Surface Chemistry, Adlerstr. 1, D-47798, Krefeld, Germany., Tian B; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China., Liu S; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China., Li J; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China., Yang C; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China., Strehmel V; Niederrhein University of Applied Sciences, Department of Chemistry, Institute for Coatings and Surface Chemistry, Adlerstr. 1, D-47798, Krefeld, Germany., Li S; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China., Matyjaszewski K; Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA-15213, USA., Yilmaz G; Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA-15213, USA.; Department of Chemistry, Faculty of Science and Letters, Istanbul Technical University, 34469, Maslak, Istanbul, Turkey., Strehmel B; Niederrhein University of Applied Sciences, Department of Chemistry, Institute for Coatings and Surface Chemistry, Adlerstr. 1, D-47798, Krefeld, Germany., Chen Z; Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Hexing Road 26, Harbin, 150040, China.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Apr 24; Vol. 63 (18), pp. e202316431. Date of Electronic Publication: 2024 Mar 25.
DOI: 10.1002/anie.202316431
Abstrakt: Carbon nanomaterials, specifically carbon dots and carbon nitrides, play a crucial role as heterogeneous photoinitiators in both radical and cationic polymerization processes. These recently introduced materials offer promising solutions to the limitations of current homogeneous systems, presenting a novel approach to photopolymerization. This review highlights the preparation and photocatalytic performance of these nanomaterials, emphasizing their application in various polymerization techniques, including photoinduced i) free radical, ii) RAFT, iii) ATRP, and iv) cationic photopolymerization. Additionally, it discusses their potential in addressing contemporary challenges and explores prospects in this field. Moreover, carbon nitrides, in particular, exhibit exceptional oxygen tolerance, underscoring their significance in radical polymerization processes and allowing their applications such as 3D printing, surface modification of coatings, and hydrogel engineering.
(© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
Databáze: MEDLINE
Externí odkaz: