Synthesis of Polymeric Mimics of Ice-Binding Proteins.
| Autor: | Sproncken CCM; Department of Chemical Engineering and Chemistry & Institute for Complex Molecular Systems, Eindhoven University of Technology, Eindhoven, the Netherlands., Detrembleur C; Center for Education and Research on Macromolecules (CERM) CESAM Research Unit, Department of Chemistry, University of Liège, Liège, Belgium., Voets IK; Department of Chemical Engineering and Chemistry & Institute for Complex Molecular Systems, Eindhoven University of Technology, Eindhoven, the Netherlands. i.voets@tue.nl. |
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| Jazyk: | angličtina |
| Zdroj: | Methods in molecular biology (Clifton, N.J.) [Methods Mol Biol] 2024; Vol. 2730, pp. 203-210. |
| DOI: | 10.1007/978-1-0716-3503-2_14 |
| Abstrakt: | Cobalt-mediated radical polymerization (CMRP) enables the preparation of both short and long polymers from acrylic and vinyl ester monomers with low dispersity. Here we describe the synthesis, purification, and characterization of polymeric mimics of ice-binding proteins based on the water-soluble polymer poly(vinyl alcohol) by CMRP. Block copolymers of poly(vinyl alcohol) and poly(acrylic acid) were prepared from the precursor copolymers poly(vinyl acetate)-b-poly(acrylonitrile) upon hydrolysis. Copolymers comprising up to hundreds of monomers and dispersities M (© 2024. The Author(s), under exclusive license to Springer Science+Business Media, LLC, part of Springer Nature.) |
| Databáze: | MEDLINE |
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