Optical Cavity Design and Functionality for Molecular Strong Coupling.
| Autor: | Hirai K; Research Institute for Electronic Science (RIES), Hokkaido University, N20 W10, Sapporo, Hokkaido, 001-0020, Japan., Andell Hutchison J; School of Chemistry and, Australian Research Council Centre of Excellence in Exciton Science, The University of Melbourne, Masson Rd, Parkville, VIC, 3052, Australia., Uji-I H; Research Institute for Electronic Science (RIES), Hokkaido University, N20 W10, Sapporo, Hokkaido, 001-0020, Japan.; Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001, Leuven, Belgium. |
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| Jazyk: | angličtina |
| Zdroj: | Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Feb 01; Vol. 30 (7), pp. e202303110. Date of Electronic Publication: 2023 Dec 12. |
| DOI: | 10.1002/chem.202303110 |
| Abstrakt: | Optical cavity/molecule strong coupling offers attractive opportunities to modulate photochemical or photophysical processes. When atoms or molecules are placed in an optical cavity, they can coherently exchange photonic energy with optical cavity vacuum fields, entering the strong coupling interaction regime. Recent work suggests that the thermodynamic and kinetic properties of molecules can be significantly changed by strong coupling, resulting in the emergence of intriguing photochemical and photophysical phenomena. As more and more physico-chemical systems are studied under strong coupling conditions, optical cavities have also advanced in their sophistication, responsiveness, and (multi)functionality. In this review, we highlight some of these recent developments, particularly focusing on Fabry-Perot microcavities. (© 2023 Wiley-VCH GmbH.) |
| Databáze: | MEDLINE |
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