| Autor: |
Wang HP; School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, P. R. China., Eichhöfer A; Institute of Nanotechnology (INT), Karlsruhe Institute of Technolgoy (KIT), Eggenstein-Leopoldshafen 76344, Germany.; Lehn Institute of Functional Materials, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, P.R. China.; Karlsruhe Nano Micro Facility (KNMFi), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany., Gu ZG; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P.R. China., Gruber N; Service de Radiocristallographie, Faculté de Chimie, 1, rue Blaise Pascal, Strasbourg, France., Stadler AM; Institute of Nanotechnology (INT), Karlsruhe Institute of Technolgoy (KIT), Eggenstein-Leopoldshafen 76344, Germany.; University of Strasbourg Institute for Advanced Study (USIAS), 5 Allée du Général Rouvillois, Strasbourg 67083, France.; Institut de Science et Ingénierie Supramoléculaires (ISIS), UMR 7006, CNRS and Université de Strasbourg, 8 Allée G. Monge, Strasbourg 67000, France. mstadler@unistra.fr. |
| Abstrakt: |
Reaction of a trinuclear triangular macrocyclic complex Pb 3 L(CF 3 SO 3 ) 6 with bidentate linkers in a ratio of 3 equiv. of linker per 2 equiv. of complex, produces a prismatic structure with 4,4'-dipyridyl, and two unprecedented, extended 3D frustum-like structures with 1,2-di(4-pyridyl)ethylene and 1,4-di(4-pyridyl)benzene. The cavities of these structures encapsulate triflate anions. |
