Diradicaloid Boron-Doped Molecular Carbons Achieved by Pentagon-Fusion.
Autor: | Yuan L; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, P. R. China., Yang J; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, P. R. China., Qi S; Key Laboratory of Forest Plant Ecology, Ministry of Education, College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, 150040, Harbin, P. R. China., Liu Y; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, P. R. China., Tian X; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, P. R. China., Jia T; Key Laboratory of Forest Plant Ecology, Ministry of Education, College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, 150040, Harbin, P. R. China., Wang Y; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, P. R. China., Dou C; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, P. R. China. |
---|---|
Jazyk: | angličtina |
Zdroj: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2023 Dec 18; Vol. 62 (51), pp. e202314982. Date of Electronic Publication: 2023 Nov 16. |
DOI: | 10.1002/anie.202314982 |
Abstrakt: | Molecular carbons (MCs) are molecular cutouts of carbon materials. Doping with heteroatoms and constructing open-shell structures are two powerful approaches to achieve unexpected and unique properties of MCs. Herein, we disclose a new strategy to design open-shell boron-doped MCs (BMCs), namely by pentagon-fusion of an organoborane π-system. We synthesized two diradicaloid BMC molecules that feature C (© 2023 Wiley-VCH GmbH.) |
Databáze: | MEDLINE |
Externí odkaz: |