Reply to the 'Comment on "CO 2 as oxidant: an unusual light-assisted catalyst free oxidation of aldehydes to acids under mild conditions"' by S. R. Khan, S. Saini, K. Naresh, A. Kumari, V. Aniya, P. K. Khatri, A. Ray and S. L. Jain, Chem. Commun ., 2022, 58 , 2208.

Autor: Khan SR; Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India. suman@iip.res.in., Saini S; Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India. suman@iip.res.in.; Academy of Scientific and Innovative Research, Ghaziabad, 201002, India., Naresh K; Process Engineering Technology Transfer Division, CSIR-Indian Institute of Chemical Technology, Hyderabad-500007, India., Kumari A; Process Engineering Technology Transfer Division, CSIR-Indian Institute of Chemical Technology, Hyderabad-500007, India., Aniya V; Process Engineering Technology Transfer Division, CSIR-Indian Institute of Chemical Technology, Hyderabad-500007, India., Khatri PK; Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India. suman@iip.res.in., Ray A; Director, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India., Jain SL; Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India. suman@iip.res.in.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Nov 23; Vol. 59 (94), pp. 14036-14039. Date of Electronic Publication: 2023 Nov 23.
DOI: 10.1039/d3cc04389d
Abstrakt: Our recent Communication (S. R. Khan et al. , Chem. Commun ., 2022, 58 , 2208) suggested that CO 2 can be used as a potential oxidant under light irradiation without using any catalyst for the oxidation of aldehydes to acids at room temperature. The Comment based on the published literature on the catalytic oxidation of aromatic aldehydes by CO 2 and thermodynamical data argued on the realism of the experimental data.
Databáze: MEDLINE
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