Spatially resolved CO 2 carbon stable isotope analyses at the microscale using Raman spectroscopy.

Autor: Remigi S; Dipartimento di Scienze dell'Ambiente e della Terra, Università Milano-Bicocca, Piazza della Scienza 4, 20126, Milan, Italy., Frezzotti ML; Dipartimento di Scienze dell'Ambiente e della Terra, Università Milano-Bicocca, Piazza della Scienza 4, 20126, Milan, Italy. maria.frezzotti@unimib.it., Rizzo AL; Dipartimento di Scienze dell'Ambiente e della Terra, Università Milano-Bicocca, Piazza della Scienza 4, 20126, Milan, Italy., Esposito R; Dipartimento di Scienze dell'Ambiente e della Terra, Università Milano-Bicocca, Piazza della Scienza 4, 20126, Milan, Italy., Bodnar RJ; Department of Geosciences, Virginia Tech, 926 West Campus Drive, Blacksburg, VA, 24061, USA., Sandoval-Velasquez A; Dipartimento di Scienze della Terra e del Mare, Università di Palermo, Via Archirafi 36, 90123, Palermo, Italy., Aiuppa A; Dipartimento di Scienze della Terra e del Mare, Università di Palermo, Via Archirafi 36, 90123, Palermo, Italy.
Jazyk: angličtina
Zdroj: Scientific reports [Sci Rep] 2023 Oct 29; Vol. 13 (1), pp. 18561. Date of Electronic Publication: 2023 Oct 29.
DOI: 10.1038/s41598-023-44903-z
Abstrakt: Measuring the carbon stable isotope ratio ( 13 C/ 12 C, expressed as δ 13 C CO2 ) in geogenic CO 2 fluids is a crucial geochemical tool for studying Earth's degassing. Carbon stable isotope analysis is traditionally performed by bulk mass spectrometry. Although Raman spectroscopy distinguishes 12 CO 2 and 13 CO 2 isotopologue bands in spectra, using this technique to determine CO 2 isotopic signature has been challenging. Here, we report on in-situ non-destructive analyses of the C stable isotopic composition of CO 2 , applying a novel high-resolution Raman configuration on 42 high-density CO 2 fluid inclusions in mantle rocks from the Lake Tana region (Ethiopia) and El Hierro (Canary Islands). We collected two sets of three spectra with different acquisition times at high spectral resolution in each fluid inclusion. Among the 84 sets of spectra, 58 were characterised by integrated 13 CO 2 / 12 CO 2 band area ratios with reproducibility better than 4‰. Our results demonstrate the determination of δ 13 C CO2 by Raman spectroscopy in individual fluid inclusions with an error better than 2.5 ‰, which satisfactorily matches bulk mass spectrometry analyses in the same rock samples, supporting the accuracy of the measurements. We thus show that Raman Spectroscopy can provide a fundamental methodology for non-destructive, site-specific, and spatially resolved carbon isotope labelling at the microscale.
(© 2023. The Author(s).)
Databáze: MEDLINE
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