Photoinduced large magnetic change at room temperature and radical-quenched spin glass in a cyanide-bridged Mn II -Fe III compound.

Autor: Cai LZ; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. gcguo@fjirsm.ac.cn., Yu XQ; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. gcguo@fjirsm.ac.cn., Wang MS; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. gcguo@fjirsm.ac.cn., Guo GC; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. gcguo@fjirsm.ac.cn.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2023 Nov 07; Vol. 52 (43), pp. 15677-15681. Date of Electronic Publication: 2023 Nov 07.
DOI: 10.1039/d3dt03080f
Abstrakt: By the coordination assembly of a redox photoactive functional motif and a cyanide-bridged moiety, a cyanide-bridged Mn II -Fe III compound with large photoinduced magnetic change at room-temperature due to photoinduced electron transfer was obtanied. This compound also shows unprecedented radical-quenched spin glass in molecule based magnets.
Databáze: MEDLINE
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