Picking the lock of coordination cage catalysis.
| Autor: | Piskorz TK; Chemistry Research Laboratory, University of Oxford Oxford OX1 3TA UK fernanda.duartegonzalez@chem.ox.ac.uk., Martí-Centelles V; Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Universitat Politècnica de València, Universitat de València Camino de Vera, s/n 46022 Valencia Spain., Spicer RL; Department of Chemistry, Lancaster University Lancaster LA14YB UK., Duarte F; Chemistry Research Laboratory, University of Oxford Oxford OX1 3TA UK fernanda.duartegonzalez@chem.ox.ac.uk., Lusby PJ; EaStCHEM School of Chemistry, University of Edinburgh Edinburgh Scotland EH9 3FJ UK Paul.Lusby@ed.ac.uk. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical science [Chem Sci] 2023 Sep 08; Vol. 14 (41), pp. 11300-11331. Date of Electronic Publication: 2023 Sep 08 (Print Publication: 2023). |
| DOI: | 10.1039/d3sc02586a |
| Abstrakt: | The design principles of metallo-organic assembly reactions have facilitated access to hundreds of coordination cages of varying size and shape. Many of these assemblies possess a well-defined cavity capable of hosting a guest, pictorially mimicking the action of a substrate binding to the active site of an enzyme. While there are now a growing collection of coordination cages that show highly proficient catalysis, exhibiting both excellent activity and efficient turnover, this number is still small compared to the vast library of metal-organic structures that are known. In this review, we will attempt to unpick and discuss the key features that make an effective coordination cage catalyst, linking structure to activity (and selectivity) using lessons learnt from both experimental and computational analysis of the most notable exemplars. We will also provide an outlook for this area, reasoning why coordination cages have the potential to become the gold-standard in (synthetic) non-covalent catalysis. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
| Databáze: | MEDLINE |
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