ArI(NTf 2 ) 2 : the boundary of oxidative capacity for ArIL 2 ?

Autor: Barwise L; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au., Bennetts JD; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au., White KF; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au., Dutton JL; Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia. j.dutton@latrobe.edu.au.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Nov 07; Vol. 59 (89), pp. 13340-13343. Date of Electronic Publication: 2023 Nov 07.
DOI: 10.1039/d3cc04563c
Abstrakt: Synthesis and crystallographic characterization of NO 2 -C 6 H 4 -I(NTf 2 ) 2 (NTf 2 = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf) 2 is unable to and theoretical analysis indicates Ar-I(NTf 2 ) 2 is the most oxidizing in the ArIL 2 class of compounds known and may also be the most oxidizing compound in the class practically possible.
Databáze: MEDLINE
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