| Autor: |
Tromans J; School of Natural & Environmental Sciences - Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK. bernard.golding@ncl.ac.uk., Zhang B; BiBerChem Research Ltd, The Biosphere, Draymans Way, Newcastle Helix, Newcastle upon Tyne, NE4 5BX, UK., Golding BT; School of Natural & Environmental Sciences - Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK. bernard.golding@ncl.ac.uk. |
| Abstrakt: |
A new benzyl-type protecting group (1,4-dimethoxynaphthalene-2-methyl, 'DIMON') for hydroxyl functions can be selectively removed under oxidative conditions without damaging polyunsaturated fatty acyl groups. Its application is shown by the first synthesis of an ether (plasmanyl) phospholipid containing the docosa-(4 Z ,7 Z ,10 Z ,13 Z ,16 Z ,19 Z )-hexaenoyl group. |
