Orthogonal chain collapse in stimuli-responsive di-block polymers leading to self-sorted nanostructures.

Autor: Miglani C; Chemical Biology Unit, Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali, Punjab, India. apal@inst.ac.in., Banoo M; Department of Chemical Sciences, IISER Mohali, Knowledge City, Sector 81, Mohali, Punjab, India. ujjalgautam@iisermohali.ac.in., Nath D; Chemical Biology Unit, Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali, Punjab, India. apal@inst.ac.in., Ralhan J; Chemical Biology Unit, Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali, Punjab, India. apal@inst.ac.in., Sil S; Department of Chemical Sciences, IISER Mohali, Knowledge City, Sector 81, Mohali, Punjab, India. ujjalgautam@iisermohali.ac.in., Joseph JP; Chemical Biology Unit, Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali, Punjab, India. apal@inst.ac.in., Pal SK; Department of Chemical Sciences, IISER Mohali, Knowledge City, Sector 81, Mohali, Punjab, India. ujjalgautam@iisermohali.ac.in., Gautam U; Department of Chemical Sciences, IISER Mohali, Knowledge City, Sector 81, Mohali, Punjab, India. ujjalgautam@iisermohali.ac.in., Pal A; Chemical Biology Unit, Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali, Punjab, India. apal@inst.ac.in.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Nov 02; Vol. 59 (88), pp. 13195-13198. Date of Electronic Publication: 2023 Nov 02.
DOI: 10.1039/d3cc04029a
Abstrakt: We design amphiphilic di-block copolymers (P-b-F and P-b-C) tethered with stimuli-responsive ferrocene and coumarin hydrophobic pendants that exhibit chain collapse behaviour in response to light, redox and chemical cues, with subsequent transformation of the vesicles into micelles. Interestingly, the co-assembled vesicles of the polymer blend under orthogonal stimuli furnish self-sorted micelles and vesicles.
Databáze: MEDLINE
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