Design and Photonics of Merocyanine Dyes.

Autor: Kulinich AV; Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Akademika Kukharya St., 02094, Kyiv, Ukraine., Ishchenko AA; Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Akademika Kukharya St., 02094, Kyiv, Ukraine.
Jazyk: angličtina
Zdroj: Chemical record (New York, N.Y.) [Chem Rec] 2024 Feb; Vol. 24 (2), pp. e202300262. Date of Electronic Publication: 2023 Oct 18.
DOI: 10.1002/tcr.202300262
Abstrakt: Merocyanines, thanks to their easily adjustable electronic structure, appear to be the most versatile and promising functional dyes. Their D-π-A framework offers ample opportunities for custom design through variations in both donor/acceptor end-groups and the π-conjugated polymethine chain, and leads to a broad range of practical properties, including noticeable solvatochromism, high polarizability/hyperpolarizabilities, and the ability to sensitize various physicochemical processes. Accordingly, merocyanines are applied and extensively studied in various fields, such as light-converting materials for optoelectronics, nonlinear optics, optical storage, solar cells, fluorescent probes, and antitumor agents in photodynamic therapy. This review encompasses both classical and novel more important publications on the structure-property relationships in merocyanines, with particular emphasis on the results by A.  I. Kiprianov and his followers in Institute of Organic Chemistry in Kyiv, Ukraine.
(© 2023 The Chemical Society of Japan & Wiley-VCH GmbH.)
Databáze: MEDLINE
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