Metals from spacecraft reentry in stratospheric aerosol particles.

Autor: Murphy DM; Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305.; Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN 47907., Abou-Ghanem M; Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305., Cziczo DJ; Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN 47907., Froyd KD; Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305.; Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309., Jacquot J; Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN 47907., Lawler MJ; Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305.; Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309., Maloney C; Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305.; Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309., Plane JMC; School of Chemistry, University of Leeds, Leeds LS29JT, United Kingdom., Ross MN; The Aerospace Corporation, El Segundo, CA 90245., Schill GP; Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305., Shen X; Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN 47907.
Jazyk: angličtina
Zdroj: Proceedings of the National Academy of Sciences of the United States of America [Proc Natl Acad Sci U S A] 2023 Oct 24; Vol. 120 (43), pp. e2313374120. Date of Electronic Publication: 2023 Oct 16.
DOI: 10.1073/pnas.2313374120
Abstrakt: Large increases in the number of low earth orbit satellites are projected in the coming decades [L. Schulz, K.-H. Glassmeier, Adv. Space Res. 67 , 1002-1025 (2021)] with perhaps 50,000 additional satellites in orbit by 2030 [GAO, Large constellations of satellites: Mitigating environmental and other effects (2022)]. When spent rocket bodies and defunct satellites reenter the atmosphere, they produce metal vapors that condense into aerosol particles that descend into the stratosphere. So far, models of spacecraft reentry have focused on understanding the hazard presented by objects that survive to the surface rather than on the fate of the metals that vaporize. Here, we show that metals that vaporized during spacecraft reentries can be clearly measured in stratospheric sulfuric acid particles. Over 20 elements from reentry were detected and were present in ratios consistent with alloys used in spacecraft. The mass of lithium, aluminum, copper, and lead from the reentry of spacecraft was found to exceed the cosmic dust influx of those metals. About 10% of stratospheric sulfuric acid particles larger than 120 nm in diameter contain aluminum and other elements from spacecraft reentry. Planned increases in the number of low earth orbit satellites within the next few decades could cause up to half of stratospheric sulfuric acid particles to contain metals from reentry. The influence of this level of metallic content on the properties of stratospheric aerosol is unknown.
Databáze: MEDLINE