Utilization of a novel PVC- optical sensor for high sensitive and selective determination of zinc ion in real samples.
Autor: | Alshehri RF; Chemistry Department, College of Science& Arts, Taibah University, Saudi Arabia., El-Feky HH; Chemistry Department, Faculty of Science, Benha University, Benha, Egypt., Askar AM; Chemistry Department, Faculty of Science, Benha University, Benha, Egypt., Amin AS; Chemistry Department, Faculty of Science, Benha University, Benha, Egypt. Electronic address: asamin2005@hotmail.com., Aish M; Chemistry Department, Faculty of Science, Port Said University, Port Said, Egypt. |
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Jazyk: | angličtina |
Zdroj: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [Spectrochim Acta A Mol Biomol Spectrosc] 2024 Jan 15; Vol. 305, pp. 123424. Date of Electronic Publication: 2023 Sep 18. |
DOI: | 10.1016/j.saa.2023.123424 |
Abstrakt: | A novel and highly specific bulk membrane optode was developed for the ultra-sensitive detection of zinc(II) in biological, pharmaceutical, and water samples. The polymer inclusion membrane (PIM) utilized in this study consists of 50% polyvinyl chloride (PVC) as a base polymer, 9.00% DOP (dioctylphthalate) as the plasticizer, and 40.0% D2EHPA (di(2-ethlyhexyl)phosphoric acid) as the carrier. To facilitate the spectrophotometric determination of zinc(II), a colorimetric reagent, namely 4-(2-arsonophenylazo) salicylic acid (APASA) {1.00%, m/v}, was employed. When Zn(II) was extracted into the PIM, it led to the creation of the zinc-D2EHPA complex. This complex then underwent a reaction with APASA, resulting in the formation of a red Zn - APASA complex with a maximum absorption wavelength (λ Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. (Copyright © 2023 Elsevier B.V. All rights reserved.) |
Databáze: | MEDLINE |
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