Influence of the Substituent's Size in the Phosphinate Group on the Conformational Possibilities of Ferrocenylbisphosphinic Acids in the Design of Coordination Polymers and Metal-Organic Frameworks.

Autor: Shekurov RP; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia., Khrizanforov MN; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.; A.M. Butlerov Chemistry Institute, Kazan Federal University, 420008 Kazan, Russia., Bezkishko IA; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia., Ivshin KA; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia., Zagidullin AA; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.; Institute of Fundamental Medicine and Biology, Kazan Federal University, 420008 Kazan, Russia., Lazareva AA; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.; A.M. Butlerov Chemistry Institute, Kazan Federal University, 420008 Kazan, Russia., Kataeva ON; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.; A.M. Butlerov Chemistry Institute, Kazan Federal University, 420008 Kazan, Russia., Miluykov VA; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.
Jazyk: angličtina
Zdroj: International journal of molecular sciences [Int J Mol Sci] 2023 Sep 14; Vol. 24 (18). Date of Electronic Publication: 2023 Sep 14.
DOI: 10.3390/ijms241814087
Abstrakt: This paper illustrates how the size and type of substituent R in the phosphinate group of ferrocenyl bisphosphinic acids can affect conformational possibilities and coordination packing. It also demonstrates that H -phosphinate plays a key role in variational mobility, while Me- or Ph- substituents of the phosphinate group can only lead to 0D complexes or 1D coordination polymer. Overall, this paper provides valuable insights into the design and construction of coordination polymers based on ferrocene-contained linkers. It sheds light on how different reaction conditions and substituents can affect conformational possibilities and coordination packing, which could have significant implications for developing new polymers with unique properties.
Databáze: MEDLINE
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