Photocatalyst- and Transition Metal-Free Light-Induced Borylation Reactions.

Autor: Bhanja R; School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute, Bhubaneswar, PO Bhimpur-Padanpur, Via Jatni, District Khurda, Odisha, 752050, India) (PM., Bera SK; School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute, Bhubaneswar, PO Bhimpur-Padanpur, Via Jatni, District Khurda, Odisha, 752050, India) (PM., Mal P; School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute, Bhubaneswar, PO Bhimpur-Padanpur, Via Jatni, District Khurda, Odisha, 752050, India) (PM.
Jazyk: angličtina
Zdroj: Chemistry, an Asian journal [Chem Asian J] 2023 Nov 02; Vol. 18 (21), pp. e202300691. Date of Electronic Publication: 2023 Oct 11.
DOI: 10.1002/asia.202300691
Abstrakt: The increasing global warming concerns have propelled a surge in the demand for sustainable energy sources within the domain of synthetic organic chemistry. A particularly prominent area of research has been the development of mild synthetic strategies for generating heterocyclic compounds. Heterocyclic compounds containing boron have notably risen to prominence as pivotal reagents in a myriad of organic transformations, showcasing their wide-ranging applicability. This comprehensive review is aimed at collecting the literature pertaining to borylation reactions induced by light, specifically focusing on photocatalyst-free and transition metal-free methodologies. The central emphasis is on delving into selective mechanistic investigations. The amalgamation and analysis of these research insights elucidate the substantial potential inherent in eco-friendly approaches for synthesizing heterocyclic compounds, thus propelling the landscape of sustainable organic chemistry.
(© 2023 Wiley-VCH GmbH.)
Databáze: MEDLINE
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