| Autor: |
Sundaresan S; Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany. rentschl@uni-mainz.de., Becker JG; Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany. rentschl@uni-mainz.de., Eppelsheimer J; Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany. rentschl@uni-mainz.de., Sedykh AE; Institute of Inorganic and Analytical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany., Carrella LM; Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany. rentschl@uni-mainz.de., Müller-Buschbaum K; Institute of Inorganic and Analytical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany., Rentschler E; Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany. rentschl@uni-mainz.de. |
| Abstrakt: |
We report the multi-step synthesis of the tetradentate 2-(naphthalen-2-yl)-5-[ N , N -bis(2-pyridylmethyl)aminomethyl]-1,3,4-oxadiazole ligand (LTetra-ODA) along with its corresponding [Fe II (LTetra-ODA)(NCBH 3 ) 2 ]·1.5CH 3 OH (C1) complex, which is the first mononuclear 1,3,4-oxadiazole based Fe(II) spin crossover (SCO) complex, and its zinc analogue [Zn II (LTetra-ODA)(NCBH 3 ) 2 ]·0.5H 2 O (C2). The spin transition is followed by variable temperature (VT-) X-ray crystallography of [Fe(LTetra-ODA)(NCBH 3 ) 2 ]·1.5CH 3 OH (C1) at 120 and 220 K. The magnetic susceptibility measurements on the bulk sample recorded from 2 to 300 K show that the complex exhibits a complete abrupt reversible spin transition with a T 1/2 of 207 K. The loss of the lattice solvent methanol shifts the T 1/2 slightly to around 210 K. The spin transition in solution for [Fe(LTetra-ODA)(NCBH 3 ) 2 ]·1.5CH 3 OH (C1) was followed using the VT- 1 H-NMR Evans method in CD 3 CN, with a T 1/2 of 357 K. Solid state VT luminescence studies provide some preliminary evidence of interplay of luminescence and spin transition in the [Fe(LTetra-ODA)(NCBH 3 ) 2 ]·1.5CH 3 OH (C1) complex. |
