N -Cyclo-hexyl-tryptamine: freebase, bromide and fumarate.

Autor: Naeem M; University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA., Le AN; University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA., Bauer BE; CaaMTech, Inc., 58 East Sunset Way, Suite 209, Issaquah, WA 98027, USA., Chadeayne AR; CaaMTech, Inc., 58 East Sunset Way, Suite 209, Issaquah, WA 98027, USA., Golen JA; University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA., Manke DR; University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2023 Jul 25; Vol. 79 (Pt 8), pp. 752-756. Date of Electronic Publication: 2023 Jul 25 (Print Publication: 2023).
DOI: 10.1107/S2056989023006217
Abstrakt: The solid-state structures of N -cyclo-hexyl-tryptamine ( I ) {systematic name: N -[2-(1 H -indol-3-yl)eth-yl]cyclo-hexa-namine}, C 16 H 22 N 2 , and two of its salts, N -cyclo-hexyl-tryptammonium bromide ( II ) {systematic name: N -[2-(1 H -indol-3-yl)eth-yl]cyclo-hexa-naminium bromide}, C 16 H 23 N 2 + ·Br - , and N -cyclo-hexyl-tryptammonium fumarate ( III ) (systematic name: bis-{ N -[2-(1 H -indol-3-yl)eth-yl]cyclo-hexa-naminium} (2 E )-but-2-enedioate), 2C 16 H 23 N 2 + ·C 4 H 2 O 4 2- , were determined by single-crystal X-ray diffraction. The freebase compound forms infinite chains along [010] through N-H⋯N hydrogen bonds. The bromide salt is held together by N-H⋯Br inter-actions in two-dimensional sheets along (001). The fumarate salt is held together in infinite three-dimensional frameworks by N-H⋯O hydrogen bonds.
(© Naeem et al. 2023.)
Databáze: MEDLINE
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