Metal-free and atom-efficient protocol for diarylation of selenocyanate by diaryliodonium salts.

Autor: Radzhabov AD; Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation. postnikov@tpu.ru., Soldatova NS; Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation. postnikov@tpu.ru., Ivanov DM; Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation. postnikov@tpu.ru.; Institute of Chemistry, Saint Petersburg State University, Saint Petersburg 199034, Russian Federation., Yusubov MS; Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation. postnikov@tpu.ru., Kukushkin VY; Institute of Chemistry, Saint Petersburg State University, Saint Petersburg 199034, Russian Federation., Postnikov PS; Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation. postnikov@tpu.ru.; Department of Solid State Engineering, Institute of Chemical Technology, Prague 16628, Czech Republic.
Jazyk: angličtina
Zdroj: Organic & biomolecular chemistry [Org Biomol Chem] 2023 Aug 23; Vol. 21 (33), pp. 6743-6749. Date of Electronic Publication: 2023 Aug 23.
DOI: 10.1039/d3ob00833a
Abstrakt: We developed an atom- and reaction mass efficient strategy for the preparation of diarylselenides using iodonium salts as reactants. The developed approach allows the obtaining of diarylselenides from the corresponding trimethoxyphenyl-substituted iodonium salts via a two-step one-pot reaction sequence. The proposed metal-free methodology is based on the involvement of both iodonium aryl groups for diarylation.
Databáze: MEDLINE
Externí odkaz: