Mixed-metal Ionothermal Synthesis of Metallophthalocyanine Covalent Organic Frameworks for CO 2 Capture and Conversion.
Autor: | Seob Song K; Department of Chemistry, University of Fribourg, Chemin du Musée 9, 1700, Fribourg, Switzerland., Fritz PW; Department of Chemistry, University of Fribourg, Chemin du Musée 9, 1700, Fribourg, Switzerland., Abbott DF; Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093, Zürich, Switzerland., Nga Poon L; Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093, Zürich, Switzerland., Caridade CM; Department of Chemistry, University of Fribourg, Chemin du Musée 9, 1700, Fribourg, Switzerland., Gándara F; Department of New Architectures in Materials Chemistry, Materials Science Institute of Madrid-CSIC, Sor Juana Inés de la Cruz 3, 28049, Madrid, Spain., Mougel V; Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093, Zürich, Switzerland., Coskun A; Department of Chemistry, University of Fribourg, Chemin du Musée 9, 1700, Fribourg, Switzerland. |
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Jazyk: | angličtina |
Zdroj: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2023 Sep 18; Vol. 62 (38), pp. e202309775. Date of Electronic Publication: 2023 Aug 11. |
DOI: | 10.1002/anie.202309775 |
Abstrakt: | Phthalocyanines (PCs) are intriguing building blocks owing to their stability, physicochemical and catalytic properties. Although PC-based polymers have been reported before, many suffer from relatively low stability, crystallinity, and low surface areas. Utilizing a mixed-metal salt ionothermal approach, we report the synthesis of a series of metallophthalocyanine-based covalent organic frameworks (COFs) starting from 1,2,4,5-tetracyanobenzene and 2,3,6,7-tetracyanoanthracene to form the corresponding COFs named M-pPPCs and M-anPPCs, respectively. The obtained COFs followed the Irving-Williams series in their metal contents, surface areas, and pore volume and featured excellent CO (© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.) |
Databáze: | MEDLINE |
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