Design and Synthesis of Bistetrazole-Based Energetic Salts Bearing the Nitrogen-Rich Fused Ring.
| Autor: | Cui WH; School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, People's Republic of China., Liu Q; School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, People's Republic of China., Ye Z; School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, People's Republic of China., He Y; School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, People's Republic of China. |
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| Jazyk: | angličtina |
| Zdroj: | Organic letters [Org Lett] 2023 Aug 04; Vol. 25 (30), pp. 5661-5665. Date of Electronic Publication: 2023 Jul 20. |
| DOI: | 10.1021/acs.orglett.3c02131 |
| Abstrakt: | A series of bistetrazole-based energetic salts bearing a nitrogen-rich fused ring were designed and synthesized. Among them, compounds 4 - 10 showed good detonation properties and excellent thermostability. By treating nitrogen-rich fused ring 3 with concentrated hydrochloric acid, a new type of Dimroth rearrangement was observed that afforded compound 12 efficiently. This new transformation herein constitutes a valuable addition to the Dimroth rearrangement. |
| Databáze: | MEDLINE |
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