Integrated System Built for Small-Molecule Semiconductors via High-Throughput Approaches.

Autor:	Wu J; Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg (HI-ERN), Immerwahrstraße 2, 91058 Erlangen, Germany.; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Zhang J; Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg (HI-ERN), Immerwahrstraße 2, 91058 Erlangen, Germany.; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Hu M; Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Eonyang-eup, Ulju-gun, Ulsan 44919, Korea., Reiser P; Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany., Torresi L; Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany., Friederich P; Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany.; Institute of Theoretical Informatics, Karlsruhe Institute of Technology (KIT), Ham Fasanengarten 5, 76131 Karlsruhe, Germany., Lahn L; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany.; Helmholtz-Zentrum Berlin GmbH, Helmholtz Institut Erlangen-Nürnberg, Cauerstraße 1, 91058 Erlangen, Germany., Kasian O; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany.; Helmholtz-Zentrum Berlin GmbH, Helmholtz Institut Erlangen-Nürnberg, Cauerstraße 1, 91058 Erlangen, Germany., Guldi DM; Department of Chemistry and Pharmacy & Interdisciplinary Center of Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058 Erlangen, Germany., Pérez-Ojeda ME; Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger-Straße 10, 91058 Erlangen, Germany., Barabash A; Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg (HI-ERN), Immerwahrstraße 2, 91058 Erlangen, Germany.; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Rocha-Ortiz JS; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Zhao Y; Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg (HI-ERN), Immerwahrstraße 2, 91058 Erlangen, Germany.; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany.; University of Electronic Science and Technology of China, School of Electronic Science and Engineering, State Key Laboratory of Electronic Thin Films and Integrated Devices, 611731 Chengdu, P. R. China., Xie Z; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Luo J; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany.; University of Electronic Science and Technology of China, School of Electronic Science and Engineering, State Key Laboratory of Electronic Thin Films and Integrated Devices, 611731 Chengdu, P. R. China., Wang Y; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Seok SI; Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Eonyang-eup, Ulju-gun, Ulsan 44919, Korea., Hauch JA; Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg (HI-ERN), Immerwahrstraße 2, 91058 Erlangen, Germany.; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany., Brabec CJ; Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg (HI-ERN), Immerwahrstraße 2, 91058 Erlangen, Germany.; Faculty of Engineering, Department of Material Science, Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Martensstrasse 7, 91058 Erlangen, Germany.
Jazyk:	angličtina
Zdroj:	Journal of the American Chemical Society [J Am Chem Soc] 2023 Aug 02; Vol. 145 (30), pp. 16517-16525. Date of Electronic Publication: 2023 Jul 19.
DOI:	10.1021/jacs.3c03271
Abstrakt:	High-throughput synthesis of solution-processable structurally variable small-molecule semiconductors is both an opportunity and a challenge. A large number of diverse molecules provide a possibility for quick material discovery and machine learning based on experimental data. However, the diversity of the molecular structure leads to the complexity of molecular properties, such as solubility, polarity, and crystallinity, which poses great challenges to solution processing and purification. Here, we first report an integrated system for the high-throughput synthesis, purification, and characterization of molecules with a large variety. Based on the principle "Like dissolves like," we combine theoretical calculations and a robotic platform to accelerate the purification of those molecules. With this platform, a material library containing 125 molecules and their optical-electronic properties was built within a timeframe of weeks. More importantly, the high repeatability of recrystallization we design is a reliable approach to further upgrading and industrial production.
Databáze:	MEDLINE
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